On Console is it possible to bind the "Vault" button and "Escape Chains" button to different buttons

I'm an idiot, and every time I try to hold the R1 button to escape chains, I inevitably end up vaulting back into Pinhead. I feel like if I could bind the two actions to different buttons it'd help a little. Does anyone know if it's possible? The controls section isn't very clear on which button is for which actions.

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